The BYD C10MS joins a full range of BYD zero-emission vehicles that have passed the Altoona test.
Two bus routes will become the UK's first to use only electric double-deck buses, beginning this fall.
The news comes as National Express confirmed 19 vehicles for its West Midlands bus operation in Birmingham.
The first five zero-emmision fully electric buses have been delivered and will begin operation in London through Metroline.
The 42-foot vehicle can accommodate up to 70 passengers.
The company's previously worked together for the production and sale of the MiDi bus.
Manufactured by Alexander Dennis Inc., the bus features 81 seats, including 53 seats on the second deck.
Vehicles offer more than 40% more seating than the 60-foot articulated buses they replaced.
The Enviro500 for Berlin will be approximately 45 feet long with three doors, two staircases, and 80 seats.
Order includes three CX35 and two CX45 models, as well as one TX model with in-seat audio.
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